Instability Constants of Complex Compounds

The present work contains instability constants for 1,381 complex compounds. We have considered it convenient to preface the summary of the instability constants with an introductory section of a general theoretical character.

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Author: K. B. Yatsimirskii

Publisher: Springer

ISBN: 1468484060

Category: Science

Page: 218

View: 834

In recent years many research workers have turned their attention to the quantitative characterization of complex compounds and reactions of complex-formation in solution. Instability constants characterize quantitatively the equili bria in solutions of complex compounds and are extensively used by chemists of widely-varying specialities, in analytical chemistry, electrochemistry, the technology of non-ferrous and rare metals, etc., for calculations of various kinds. Despite the wealth of numerical data, no reasonably full coliection of instability constants of complex compounds has been made until now. The various individual collections of data are far from complete and in most cases omit references to the source materials. Moreover, the present state of the chemistry of complex compounds most urgently demands the complete systematization of data on instability constants and an extension of work in this field which would take advantage of the latest physico-chemical methods. The present work contains instability constants for 1,381 complex compounds. We have considered it convenient to preface the summary of the instability constants with an introductory section of a general theoretical character. This section deals with methods for the calculation of instability constants from experimental data, the influence of external conditions, such as temperature and ionic strength, on the stability of com plexes, and the principal factors determining the stability of complex compounds in aqueous solution. (vii) PREFACE In compiling the summary we have used the original litera ture and abstracts for the most part up to 1954, and some work published in 1955-1956.

An Introduction to the Chemistry of Complex Compounds

The book will be of great use to chemists and chemical engineers.

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Author: Aleksander Abramovich Grinberg

Publisher: Elsevier

ISBN: 9781483184661

Category: Science

Page: 386

View: 532

An Introduction to the Chemistry of Complex Compounds discusses the fundamental concepts that are essential in understanding the underlying principles of complex compounds. The coverage of the book includes the compounds of the hexa, penta, and tetrammine type; compounds of the tri, dl, monoamine and hexacido types for the coordination number of 6; and complex compounds with a coordination number of 4. The text also covers the effects and chemical properties of complex compounds, such as the nature of the force of complex formation; the mutual effects of coordinated groups; and acid-base properties, oxidation-reduction properties, and solution equilibriums of complex compounds. The book will be of great use to chemists and chemical engineers.

The Chemistry of the Inorganic Complex Compounds

We see all the important possibilities most clearly in the following table of the various cobalt complexes . The regularities which are observed in this series hold good for all complex compounds . Formula The Complex is a V - R = W3 ...

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Author: Robert Schwarz

Publisher:

ISBN: UCAL:B4059228

Category: Chemistry, Inorganic

Page: 82

View: 294

A System of Instruction in Qualitative Chemical Analysis

95 oxide , detection of , in soluble simple compounds 184 , 185 in insoluble simple compounds 196 in soluble complex compounds 198 , 199 , 201 in insoluble complex compounds 222 , 223 in organic matters . 256 in sinter deposits 241 ...

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Author: C. Remigius Fresenius

Publisher:

ISBN: UCAL:$B46031

Category: Analytical chemistry

Page: 310

View: 904

Technical Abstract Bulletin

AD - 273 694 62-2-6 DIV , 25 ( COMPLEX IONS . TONS COMPLEX COMPOUNDS . CHLORIDES . AMINES . COBALT COMPOUNDS . DISPLACEMENT REACTIONS , CHEMICAL REACTIONS WATER REACTION KINETICS : TEMPERATURE HYDROGEN TON CONCENTRATION SPECTROGRAPHIC ...

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Author: Defense Documentation Center (U.S.)

Publisher:

ISBN: UCBK:C052215220

Category: Science

Page:

View: 536

Manual of Qualitative Chemical Analysis

Cadmium , properties of 147 oxide , detection of , in simple compounds 261 in complex compounds 299 deportment with agents 147 Cæstum , oxide , deportment with reagents 99 detection of 884 Carbon , detection of , in compound bodies 276 ...

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Author: C. Remigius Fresenius

Publisher:

ISBN: HARVARD:32044097020200

Category: Analytical chemistry

Page: 434

View: 186

MANUAL OF QUALITATIVE CHEMICAL ANALYSIS

143 oxide , deportment with reagents 143 detection of , in wimple compounds 202 in complex compounds . 259 in sinter deposits 335 sulphate ( as reagent ) 76 Crenic acid , detection oï , in soils 312 in mineral waters 337 Crystallization ...

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Author: DR. C. REMIGIUS FRESENUIS

Publisher:

ISBN: UOMDLP:ajn9288:0001.001

Category:

Page:

View: 236

Theory and Structure of Complex Compounds

This text then examines the redox potentials for the manganese hematoporphyrin in a water solution. Other chapters consider the results of applying the treatment to the hexacarbonyls of chromium, tungsten, and molybdenum.

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Author: B. Jeżowska-Trzebiatowska

Publisher: Elsevier

ISBN: 9781483280950

Category: Science

Page: 720

View: 840

Theory and Structure of Complex Compounds presents the development of the chemistry of complex compounds. This book discusses the various applications of complex compounds in the laboratories and industry, particularly for preparation of reactor materials, for identification of chemical elements, and extraction of rare elements. Organized into 88 chapters, this book begins with an overview of the essential role that oxygen plays in chemical compounds, particularly in complex compounds. This text then examines the redox potentials for the manganese hematoporphyrin in a water solution. Other chapters consider the results of applying the treatment to the hexacarbonyls of chromium, tungsten, and molybdenum. This book discusses as well the optical rotatory dispersion of asymmetric organic and inorganic compounds. The final chapter deals with the general equation allowing determination of the equilibrium constants of the complex formation reaction from spectro-photometric measurements. This book is a valuable resource for chemists, physicists, scientists, and mathematicians.

U S Government Research Reports

AD - 404 779 63-3-5 DIV , 4 COMPLEX COMPOUNDS GOLD COMPOUNDS SYNTHESIS OF COMPLEX GOLD ( 3T ) VITH THE TRIDENTATE LIGAND ... AD - 412 908 63-4.4 DIV , 4 COMPLEX COMPOUND S SOLVENT ACTION FORMATION CONSTANTS AND ABSORPTIVITIES FOR ...

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Author:

Publisher:

ISBN: OSU:32435060268141

Category: Science

Page:

View: 320

General Chemistry

To state rules for naming cation complexes, anion complexes and neutral complexes with examples. 19. To end the chapter with brief summary. NEED FOR THE CHAPTER Complex compounds containing mainly transition metals have a major role in ...

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Author: S. Ekambaram

Publisher: Pearson Education India

ISBN: 9789332514164

Category: Chemistry

Page: 645

View: 513

General Chemistry presents the fundamental concepts of general chemistry in a precise and comprehensive manner for undergraduate students of chemistry and life science at all Indian universities. Adhering strictly to the UGC curriculum, the contents are written in a simple and lucid language enriched with a large number of examples and illustrations.

Technical Translations

Order from SLA $ 1.60 63-10102 chloride , * Vanadium compounds , * Titanium compounds , * Neodymium compounds ... for the explanation of thermodynamic and kinetic properties of complex compounds , by K. B. Yatsimirskii Behavior of ...

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Author:

Publisher:

ISBN: UOM:39015024295241

Category: Periodicals

Page:

View: 496

English Compounds and their Spelling

5.12.3 Hypothesis L3 – Complex Compounds Complex compounds disfavour solid spelling. ... general hypothesis is based on the assumption that a large degree of complexity makes the recognition of a compound's constituents more difficult.

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Author: Christina Sanchez-Stockhammer

Publisher: Cambridge University Press

ISBN: 9781107197848

Category: Language Arts & Disciplines

Page: 280

View: 738

An original study of the formation of compounds, and what syntactic, structural and semantic criteria determine their spelling and usage.

Laboratory Methods of Inorganic Chemistry

Since manifestly every compound containing more than two elements can under certain conditions behave in such a manner as to indicate the grouping of two of its constituents into a complex , it appears more rational to include under ...

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Author: Heinrich Biltz

Publisher:

ISBN: UCAL:$B35407

Category: Chemistry

Page: 258

View: 133

Selected Topics in Inorganic Chemistry

( ii ) Coordination ( or complex ) compounds . It has been observed that when solutions of Fe ( CN ) , and KCN are mixed together and evaporated , potassium ferrocyanide , Fe ( CN ) , 4KCN is obtained which in aqueous solution does not ...

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Author: Wahid U Malik | GD Tuli | RD Madan

Publisher: S. Chand Publishing

ISBN: 8121906008

Category: Science

Page: 789

View: 651

Selected Topics in Inorganic Chemistry is a comprehensive textbook discussing theoretical aspects of Inorganic Chemistry. Uniqueness of the book lies in treatment of all fundamental concepts, such as, Structure of Atom, Chemical Bonding, Inner Transition Elements and Coordination Chemistry, with a modern approach. Illustration of text with relevant line diagrams and tabular presentation of data makes understanding of concepts lucid and simple. The book is designed for B.Sc. (Honours) and M.Sc. students.

Vinyl Compounds Advances in Research and Application 2013 Edition

However, generally speaking, organic compounds have a tendency to decompose with time, so that the indicators making use of ... Compared with the temperature indicating members containing mercury-containing halogen complex compound, ...

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Author:

Publisher: ScholarlyEditions

ISBN: 9781481681179

Category: Science

Page: 797

View: 108

Vinyl Compounds—Advances in Research and Application: 2013 Edition is a ScholarlyBrief™ that delivers timely, authoritative, comprehensive, and specialized information about ZZZAdditional Research in a concise format. The editors have built Vinyl Compounds—Advances in Research and Application: 2013 Edition on the vast information databases of ScholarlyNews.™ You can expect the information about ZZZAdditional Research in this book to be deeper than what you can access anywhere else, as well as consistently reliable, authoritative, informed, and relevant. The content of Vinyl Compounds—Advances in Research and Application: 2013 Edition has been produced by the world’s leading scientists, engineers, analysts, research institutions, and companies. All of the content is from peer-reviewed sources, and all of it is written, assembled, and edited by the editors at ScholarlyEditions™ and available exclusively from us. You now have a source you can cite with authority, confidence, and credibility. More information is available at http://www.ScholarlyEditions.com/.

Hawaiian Planters Record

All of the required elements occur in nature either singly or in simple compounds which are practically stable under natural conditions . In the living protoplası they are put together in various complex combinations and compounds which ...

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Author:

Publisher:

ISBN: UCAL:C3037888

Category: Sugar

Page:

View: 151

Library of Congress Subject Headings

... Complex Diet , Complex carbohydrate BT Diet therapy Food — Carbohydrate content High - fiber diet Reducing diets -Recipes UF Complex carbohydrate cookery BT Cookery Complex compounds ( May Subd Geog ) IQD474 UF Complexes ( Chemistry ) ...

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Author: Library of Congress. Cataloging Policy and Support Office

Publisher:

ISBN: UOM:39015048651866

Category: Subject headings, Library of Congress

Page:

View: 932

Library of Congress Subject Headings

... Recipes UF Complex carbohydrate cookery BT Cookery Complex compounds ( May Subd Geog ) QD4741 UF Complexes ( Chemistry ) Compounds , Complex NT Clathrate compounds Complexometric titration Coordination compounds Crystal field theory ...

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Author: Library of Congress

Publisher:

ISBN: WISC:89104096987

Category: Subject headings, Library of Congress

Page:

View: 372

Fluorine Its Compounds and Air Pollution

The alkaline filter paper method collected more fluoride compounds than the impinger method . ... The fluoride ion compound in water was not absorbed with ECTEOLA but the hexafluorosilicate complex in the same solution was adsorbed with ...

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Author: Air Pollution Technical Information Center

Publisher:

ISBN: UCAL:B4193541

Category: Air

Page: 597

View: 993