Ionic Liquids

In this volume, recent advances in a number of these different areas are reported and reviewed, thus granting some appreciation for the future that ionic liquid research holds and affording inspiration for those who have not previously ...

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Author: Scott Handy

Publisher: BoD – Books on Demand

ISBN: 9789535129011

Category: Science

Page: 606

View: 235

Ionic liquids, including the newer subcategory of deep eutectic solvents, continue to attract a great deal of research attention in an even increasing number of areas, including traditional areas such as synthesis (organic and materials), electrochemistry, and physical property studies and predictions, as well as less obvious areas such as lubrication and enzymatic transformations. In this volume, recent advances in a number of these different areas are reported and reviewed, thus granting some appreciation for the future that ionic liquid research holds and affording inspiration for those who have not previously considered the application of ionic liquids in their area of interest.

Supported Ionic Liquids

This unique book gives a timely overview about the fundamentals and applications of supported ionic liquids in modern organic synthesis.

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Author: Rasmus Fehrmann

Publisher: John Wiley & Sons

ISBN: 9783527324293

Category: Science

Page: 496

View: 112

This unique book gives a timely overview about the fundamentals and applications of supported ionic liquids in modern organic synthesis. It introduces the concept and synthesis of SILP materials and presents important applications in the field of catalysis (e.g. hydroformylation, hydrogenation, coupling reactions, fine chemical synthesis) as well as energy technology and gas separation. Written by pioneers in the field, this book is an invaluable reference book for organic chemists in academia or industry.

Ionic Liquids Properties and Applications

This article collection is dedicated to Prof. Kenneth R. Seddon for his outstanding contribution to the formation and development of the ionic liquids community.

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Author: Francesca D’Anna

Publisher: Frontiers Media SA

ISBN: 9782889630059

Category:

Page:

View: 444

Sustainability, defined as the way to meet the needs of the present generation without compromising the ability of future ones to meet their own, is one of the main challenges of modern society. Within this context, chemistry plays a significant role, and solvent nature as well as its environmental impact are pivotal issues frequently addressed. Ionic liquids, i.e. organic salts that have melting temperatures lower than 100 °C, have been frequently hailed as alternatives to conventional organic solvents. Their greenness has been mainly ascribed to their low vapor pressure and flammability. However, in addition to this, their high solubilizing ability and low miscibility with conventional organic solvents frequently allow for reducing the amount used, as well as for their recycling. Ionic liquids, especially the ones featured by aromatic cations, are frequently described as “polymeric supramolecular fluids” constructed through the establishment of feeble but cooperative supramolecular interactions like Coulomb and π-π interactions, as well as hydrogen bonds. In general, ionic liquids are also indicated as “designer solvents” as it is possible to tailor their features to specific applications by simply modifying their cation or anion structure. In this way, small changes in the ion’s structure can give rise to solvents showing very different properties. The above premises widely justify the growing interest in the properties and applications of ionic liquids, seen in recent literature (according to Scopus, more than 27,000 papers published in the last five years have “ionic liquids” as a keyword). Thanks to their properties, they have been variously used as solvent media, solvents for the obtainment of gel phases, components in the building of dye-sensitized solar cells, media for the preparation of thermochromic materials, etc. This Research Topic aims to present how structural features can determine not only the properties of ionic liquids, but also their possible employment. In this latter case, the interest arises from their ability to affect the outcome of a given reaction in terms of rate, yield, and nature of the products obtained for general use in the field of materials chemistry. This article collection is dedicated to Prof. Kenneth R. Seddon for his outstanding contribution to the formation and development of the ionic liquids community.

Ionic Liquids

This book is the second in the series of publications in this field by this publisher, and contains a number of latest research developments on ionic liquids (ILs).

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Author: Alexander Kokorin

Publisher: BoD – Books on Demand

ISBN: 9789533072487

Category: Science

Page: 688

View: 425

This book is the second in the series of publications in this field by this publisher, and contains a number of latest research developments on ionic liquids (ILs). This promising new area has received a lot of attention during the last 20 years. Readers will find 30 chapters collected in 6 sections on recent applications of ILs in polymer sciences, material chemistry, catalysis, nanotechnology, biotechnology and electrochemical applications. The authors of each chapter are scientists and technologists from different countries with strong expertise in their respective fields. You will be able to perceive a trend analysis and examine recent developments in different areas of ILs chemistry and technologies. The book should help in systematization of knowledges in ILs science, creation of new approaches in this field and further promotion of ILs technologies for the future.

Green Solvents

This book covers themes from the synthesis of ionic liquids, to specific uses (catalysis, separation technologies, adsorption chillers and lubricants) and includes actual case studies from industry.

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Author: Paul T. Anastas

Publisher: John Wiley & Sons

ISBN: 9783527325924

Category: Science

Page: 365

View: 422

This volume covers everything readers need to know about green chemistry. It covers topics including green chemistry engineering, green catalysis (homogeneous, heterogeneous and biocatalysis) and separations techniques as well as solvents like supercritical fluids and ionic liquids.

Ionic Liquids

See Table of Contents (PMP) See Table of Contents (PMP)

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Author: Barbara Kirchner

Publisher: Springer Science & Business Media

ISBN: 9783642017797

Category: Science

Page: 345

View: 790

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Ionic Liquids in Synthesis

This volume brings together the latest developments in this fascinating field, supplemented by numerous practical tips, and thus provides those working in both research and industry with an indispensable source of information.

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Author: Peter Wasserscheid

Publisher: John Wiley & Sons

ISBN: 9783527605446

Category: Science

Page: 380

View: 572

The demand for increasingly clean and efficient chemical syntheses is becoming more urgent from both an economic and an environmental standpoint. Many technologies rely on large quantities of hazardous even toxic solvents. A promising and now established approach is the development of new, ionic solvents that are fluid at room temperature. These solvents not only have the potential to increase chemical reactivity and thus lead to more efficient processes, but are also non-flammable and are less toxic than conventional solvents due to their low vapor pressure. This volume brings together the latest developments in this fascinating field, supplemented by numerous practical tips, and thus provides those working in both research and industry with an indispensable source of information.

Commercial Applications of Ionic Liquids

This book provides an overview of the current and emerging industrial applications of ionic liquids, covering the core processes, the practical implementation and technical challenges involved, and exploring potential future directions for ...

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Author: Mark B. Shiflett

Publisher: Springer Nature

ISBN: 9783030352455

Category: Science

Page: 288

View: 226

This book provides an overview of the current and emerging industrial applications of ionic liquids, covering the core processes, the practical implementation and technical challenges involved, and exploring potential future directions for research and development. The introductory chapter describes the unique physical and chemical properties of ionic liquids, and illustrates the vast potential for application of these materials across the industrial landscape. Following this, individual chapters written by leading figures from industry and academia address specific processes and products, such as the development of a new chloroaluminate ionic liquid as an alkylation catalyst and a new class of capillary gas chromatography (GC) columns with stationary phases based on ionic liquids. Over the past twenty years, ionic liquids have moved from being considered as mere academic curiosities to having genuine applications in fields as wide-ranging as biotechnology, biorefineries, catalysis, pharmaceuticals, renewable fuels, and sustainable energy. This book highlights several commercial products and processes that use or will soon be using ionic liquids.

Electrodeposition from Ionic Liquids

Reflecting the dramatic rise in interest shown in this field over the last few years, this book collates the widespread knowledge into one handy volume.

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Author: Frank Endres

Publisher: John Wiley & Sons

ISBN: 9783527622924

Category: Technology & Engineering

Page: 410

View: 998

Reflecting the dramatic rise in interest shown in this field over the last few years, this book collates the widespread knowledge into one handy volume. It covers in depth all classes of ionic liquids thus far in existence, with the individual chapters written by internationally recognized experts. The text is written to suit several levels of difficulty, containing information on basic physical chemistry in ionic liquids, a theory on the conductivity as well as plating protocols suited to undergraduate courses. The whole is rounded off with an appendix providing experimental procedures to enable readers to experiment with ionic liquids for themselves.

Ionic Liquids

This book includes nearly all known pure ILs and their known physicochemical properties through June 2008. In addition, the authors incorporate the main applications of individual ILs and a large number of references.

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Author: Suojiang Zhang

Publisher: Elsevier

ISBN: 0080959075

Category: Science

Page: 520

View: 324

This comprehensive database on physical properties of pure ionic liquids (ILs) contains data collected from 269 peer-reviewed papers in the period from 1982 to June 2008. There are more than 9,400 data points on the 29 kinds of physicochemical properties for 1886 available ionic liquids, from which 807 kinds of cations and 185 kinds of anions were extracted. This book includes nearly all known pure ILs and their known physicochemical properties through June 2008. In addition, the authors incorporate the main applications of individual ILs and a large number of references. Nearly 50 tables include typical data, experimental and modelling or simulation comparison, and model parameters, enhancing the application of ILs 100 figures--from QSPR, EOS and gE models to quantum and molecular simulations--help readers understand ILs at molecular level Applications illustrate the role of IL properties in industry, in particular the development of novel clean processes and products

Applications of Ionic Liquids in Polymer Science and Technology

This book summarizes the latest knowledge in the science and technology of ionic liquids and polymers in different areas.

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Author: David Mecerreyes

Publisher: Springer

ISBN: 9783662449035

Category: Science

Page: 387

View: 977

This book summarizes the latest knowledge in the science and technology of ionic liquids and polymers in different areas. Ionic liquids (IL) are actively being investigated in polymer science and technology for a number of different applications. In the first part of the book the authors present the particular properties of ionic liquids as speciality solvents. The state-of-the art in the use of ionic liquids in polymer synthesis and modification reactions including polymer recycling is outlined. The second part focuses on the use of ionic liquids as speciality additives such as plasticizers or antistatic agents. The third part examines the use of ionic liquids in the design of functional polymers (usually called polymeric ionic liquids (PIL) or poly(ionic liquids)). Many important applications in diverse scientific and industrial areas rely on these polymers, like polymer electrolytes in electrochemical devices, building blocks in materials science, nanocomposites, gas membranes, innovative anion sensitive materials, smart surfaces, and a countless set range of emerging applications in different fields such as energy, optoelectronics, analytical chemistry, biotechnology, nanomedicine or catalysis.

Ionic Liquids II

Each review within the volume critically surveys one aspect of that topic and places it within the context of the volume as a whole.

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Author: Barbara Kirchner

Publisher: Springer

ISBN: 9783319897943

Category: Science

Page: 289

View: 805

​The series Topics in Current Chemistry Collections presents critical reviews from the journal Topics in Current Chemistry organized in topical volumes. The scope of coverage is all areas of chemical science including the interfaces with related disciplines such as biology, medicine and materials science. The goal of each thematic volume is to give the non-specialist reader, whether in academia or industry, a comprehensive insight into an area where new research is emerging which is of interest to a larger scientific audience. Each review within the volume critically surveys one aspect of that topic and places it within the context of the volume as a whole. The most significant developments of the last 5 to 10 years are presented using selected examples to illustrate the principles discussed. The coverage is not intended to be an exhaustive summary of the field or include large quantities of data, but should rather be conceptual, concentrating on the methodological thinking that will allow the non-specialist reader to understand the information presented. Contributions also offer an outlook on potential future developments in the field. The chapters “Ionic Liquid–Liquid Chromatography: A New General Purpose Separation Methodology”, “Proteins in Ionic Liquids: Current Status of Experiments and Simulations”, “Lewis Acidic Ionic Liquids” and "Quantum Chemical Modeling of Hydrogen Bonding in Ionic Liquids" are available open access under a Creative Commons Attribution 4.0 International License via link.springer.com.

Nanocatalysis in Ionic Liquids

Edited and written by renowned experts in the field, this is the first book to reflect the state of the art of nanocatalysis in ionic liquids.

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Author: Martin H. G. Prechtl

Publisher: John Wiley & Sons

ISBN: 9783527339105

Category: Technology & Engineering

Page: 328

View: 925

Edited and written by renowned experts in the field, this is the first book to reflect the state of the art of nanocatalysis in ionic liquids. Divided into two core areas, the first part of the book describes the different classes of metal nanoparticles as well as their synthesis in ionic liquids, while the second focuses on such emerging issues as the application of such systems to energy and biomass conversion.

Ionic Liquid Devices

The book provides a comprehensive resource aimed at researchers and students in materials science, polymer science, chemistry and physics interested in the materials and inspire the discovery of new applications of ionic liquids in smart ...

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Author: Ali Eftekhari

Publisher: Royal Society of Chemistry

ISBN: 9781788011815

Category: Ionic solutions

Page: 455

View: 659

Ionic liquids are attractive because they offer versatility in the design of organic salts. As ion-rich media, ionic liquids can control the systems properties by tuning the size, charge, and shape of the composing ions. Whilst the focus has mainly been on the potential applications of ionic liquids as solvents, they also provide innovative opportunities for designing new systems and devices. Limitations from the high viscosity and expensive purification of the ionic liquids are also not a barrier for applications as devices. Written by leading authors, Ionic Liquid Devices introduces the innovative applications of ionic liquids. Whilst the first chapters focus on their characterization, which can be difficult in some instances, the rest of the book demonstrates how ionic liquids can play substantial roles in quite different systems from sensors and actuators to biomedical applications. The book provides a comprehensive resource aimed at researchers and students in materials science, polymer science, chemistry and physics interested in the materials and inspire the discovery of new applications of ionic liquids in smart devices.

Molten Salts and Ionic Liquids

This important new work presents twenty-six chapters contributed by a panel of experts in their respective fields, covering the structure, dynamics, chemistry, and interfacial and thermodynamic properties of molten salts and ionic liquids.

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Author: Marcelle Gaune-Escard

Publisher: John Wiley & Sons

ISBN: 9780470947760

Category: Science

Page: 250

View: 869

For many years, the related fields of molten salts and ionic liquids have drifted apart, to their mutual detriment. Both molten salts and ionic liquids are liquid salts containing only ions - all that is different is the temperature! Both fields involve the study of Coulombic fluids for academic and industrial purposes; both employ the same principles; both require skilled practitioners; both speak the same language; all then that is truly different is their semantics, and how superficial is that? The editors of this book, recognising that there was so much knowledge, both empirical and theoretical, which can be passed from the molten salt community to the ionic liquid community, and vice versa, organised a landmark meeting in Tunisia, designed to bridge the gap and heal the rift. Leaders from both communities met for a week for a mutual exchange, with a high tutorial content intermixed with cutting edge findings. This volume is a condensate of the principal offerings of that week, and emphasises the success which was achieved. Indeed, four future biannual meetings, under the title of “EUCHEM Conferences on Molten Salts and Ionic Liquids”, have now been planned as a direct result of this meeting of minds. Topics discussed in this volume include structure, dynamics, electrochemistry, interfacial and thermodynamic properties, spectroscopy, synthesis, and theoretical studies. Experimental and theoretical methods for investigating these data are elaborated, as are techniques for data collection and analysis. This book represents the first serious discussion on the transfer of these methods and techniques between the differing temperature regimes, and is a major contribution to the future of both fields.

Fundamentals of Ionic Liquids

The book begins by examining what it is that defines ionic liquids and what sets them apart from other materials.

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Author: Douglas R. MacFarlane

Publisher: John Wiley & Sons

ISBN: 9783527339990

Category: Science

Page: 258

View: 797

Written by experts who have been part of this field since its beginnings in both research and academia, this textbook introduces readers to this evolving topic and the broad range of applications that are being explored. The book begins by examining what it is that defines ionic liquids and what sets them apart from other materials. Chapters describe the various types of ionic liquids and the different techniques used to synthesize them, as well as their properties and some of the methods used in their measurement. Further chapters delve into synthetic and electrochemical applications and their broad use as "Green" solvents. Final chapters examine important applications in a wide variety of contexts, including such devices as solar cells and batteries, electrochemistry, and biotechnology. The result is a must-have resource for any researcher beginning to work in this growing field, including senior undergraduates and postgraduates.

Applications of Ionic Liquids in Science and Technology

This volume, of a two volume set on ionic liquids, focuses on the applications of ionic liquids in a growing range of areas.

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Author: Scott Handy

Publisher: BoD – Books on Demand

ISBN: 9789533076058

Category: Science

Page: 530

View: 315

This volume, of a two volume set on ionic liquids, focuses on the applications of ionic liquids in a growing range of areas. Throughout the 1990s, it seemed that most of the attention in the area of ionic liquids applications was directed toward their use as solvents for organic and transition-metal-catalyzed reactions. Certainly, this interest continues on to the present date, but the most innovative uses of ionic liquids span a much more diverse field than just synthesis. Some of the main topics of coverage include the application of RTILs in various electronic applications (batteries, capacitors, and light-emitting materials), polymers (synthesis and functionalization), nanomaterials (synthesis and stabilization), and separations. More unusual applications can be noted in the fields of biomass utilization, spectroscopy, optics, lubricants, fuels, and refrigerants. It is hoped that the diversity of this volume will serve as an inspiration for even further advances in the use of RTILs.

Application of Ionic Liquids on Rare Earth Green Separation and Utilization

This book comprehensively details the applications of ionic liquids in rare earth green separation and utilization based on the unique interactions of ionic liquids with rare earth ions.

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Author: Ji Chen

Publisher: Springer

ISBN: 9783662475102

Category: Science

Page: 257

View: 430

This book comprehensively details the applications of ionic liquids in rare earth green separation and utilization based on the unique interactions of ionic liquids with rare earth ions. It consists of nine chapters demonstrating the synthesis and properties of ionic liquids, coordination chemistry of ionic liquids and rare earth, ionic liquids as diluents, extractants, adsorption resins for rare earth extraction and separation, electrodeposition of rare earth metals in ionic liquids, and preparation of rare earth material with the aid of ionic liquids. It is both interesting and useful to chemists, metallurgists and graduate students working on fundamental research of ionic liquids as well as professionals in the rare earth industry. It provides considerable insights into green chemistry and sustainable processes for rare earth separation in order to meet the environmental challenge of rare earth metallurgy around the globe, especially in China. Ji Chen is a Professor of Chemistry at the Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, China.

Ionic Liquids in Chemical Analysis

5.7.3 Surface-confined ionic liquids as ion exchange-based stationary phases in
liquid chromatography .................... 176 5.7.4 Surface-confined ionic liquid
stationary phases in liquid chromatography as model systems for liquid–liquid ...

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Author: Mihkel Koel

Publisher: CRC Press

ISBN: 9781420046472

Category: Science

Page: 448

View: 396

An Overview of a Rapidly Expanding Area in Chemistry Exploring the future in chemical analysis research, Ionic Liquids in Chemical Analysis focuses on materials that promise entirely new ways to perform solution chemistry. It provides a broad overview of the applications of ionic liquids in various areas of analytical chemistry, in

Ionic Liquids

The current book brings together the latest developments in the area of ionic liquids, including synthesis, purity control, toxicity, and scaling-up technologies.

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Author: Rasmus Fehrmann

Publisher: Walter de Gruyter GmbH & Co KG

ISBN: 9783110582123

Category: Science

Page: 175

View: 307

The current book brings together the latest developments in the area of ionic liquids, including synthesis, purity control, toxicity, and scaling-up technologies. In addition, the authors explore the applications of ionic liquids in organic synthesis and catalysis, separation techniques and nanomaterials engineering. Written by key experts in the field, this book is an invaluable material for organic and green chemists in academia and industry.